[1]宋昆鹏,邹志娟,唐 成,等.有机微囊的控制合成及负载Pt纳米颗粒催化剂用于加氢研究[J].西华师范大学学报(自然科学版),2019,40(01):60-64.[doi:10.16246/j.issn.1673-5072.2019.01.010]
 SONG Kunpeng,ZOU Zhijuan,TANG Cheng,et al.Controlled Synthesis of Organic Capsule and Support PtNanoparticles in Hydrogenation Application[J].Journal of China West Normal University(Natural Sciences),2019,40(01):60-64.[doi:10.16246/j.issn.1673-5072.2019.01.010]
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有机微囊的控制合成及负载Pt纳米颗粒催化剂用于加氢研究

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《西华师范大学学报(自然科学版)》[ISSN:1673-5072/CN:51-1699/N]

卷:
40
期数:
2019年01期
页码:
60-64
栏目:
出版日期:
2019-03-20

文章信息/Info

Title:

Controlled Synthesis of Organic Capsule and Support PtNanoparticles in Hydrogenation Application

作者:

宋昆鹏邹志娟唐  成付玉芳

(西华师范大学 化学化工学院,四川 南充  637009)

Author(s):

SONG KunpengZOU ZhijuanTANG ChengFU Yufang

(College of Chemistry and Chemical Engineering,China West Normal University,Nanchong Sichuan 637009,China)

关键词:

有机微囊Pt纳米颗粒微孔聚合物催化加氢选择性

Keywords:

organic capsulePt nanoparticlesmicroporous organic polymercatalytic hydrogenationselectivity

分类号:
O643.3
DOI:
10.16246/j.issn.1673-5072.2019.01.010
文献标志码:
A
摘要:

设计并合成了一种中空有机微囊结构聚合物HMOCs,并通过负载Pt纳米颗粒制备了HMOCsPt(0)催化剂,采用TEM、XRD等表征手段对该催化剂进行了测试。该催化剂在苯甲醛加氢反应中表现出高效的催化活性,35 ℃下能够有效催化苯甲醛加氢到苯甲醇,收率达到99%,而且催化剂能够循环使用10次,催化性能依然保持在90%以上。

Abstract:

A hollow microporous organic capsule has been successfully designed and synthesized.The catalyst HMOCs-Pt(0) is prepared by embedding with Pt nanoparticles and tested by TEM and XRD characterization.The heterogeneous catalyst HMOCs-Pt(0) exhibits excellent catalytic activity and recyclability potential.Under 35 ℃,it can effectively catalyzes benzaldehyde hydrogenation into benzyl alcohol at 99%.Its catalytic performance maintains at 90% and above even after being recycled for 10 times.

备注/Memo

备注/Memo:

收稿日期:2018-07-17
基金项目:国家级大学生创新创业训练计划项目(201710638031);西华师范大学一般培育项目(17C038);西华师范大学英才科研基金项目(17YC031)
作者简介:宋昆鹏(1988—),男,河南信阳人,博士,讲师,硕士生导师,主要从事微孔材料与多相催化研究。
通信作者:宋昆鹏,E-mail:song19880405@126.com

更新日期/Last Update: 2018-12-20