[1]夏林,詹豪强,蒋晓慧.PANIAg/AgCl的制备及其光催化性能的研究[J].西华师范大学学报(自然科学版),2017,38(01):63-67.[doi:10.16246/j.issn.1673-5072.2017.01.011]
 XIA Lin,ZHAN Haoqiang,JIANG Xiaohui.On the Synthesis of PANIAg/AgCl and its Photocatalytic Properties[J].Journal of China West Normal University(Natural Sciences),2017,38(01):63-67.[doi:10.16246/j.issn.1673-5072.2017.01.011]
点击复制

PANIAg/AgCl的制备及其光催化性能的研究()
分享到:

《西华师范大学学报(自然科学版)》[ISSN:1673-5072/CN:51-1699/N]

卷:
38
期数:
2017年01期
页码:
63-67
栏目:
出版日期:
2017-03-20

文章信息/Info

Title:
On the Synthesis of PANIAg/AgCl and its Photocatalytic Properties
作者:
夏林詹豪强蒋晓慧
(西华师范大学 化学化工学院,四川 南充637009)
Author(s):
XIA LinZHAN HaoqiangJIANG Xiaohui
(College of Chemistry and Chemical Engineering,China West Normal University,Nanchong Sichuan 637009,China)
关键词:
Ag/AgCl 聚苯胺 甲基橙 光催化 循环利用
Keywords:
Ag/AgClPolyanilineMethyl orangePhotocatalysisRecycling
分类号:
O643.3
DOI:
10.16246/j.issn.1673-5072.2017.01.011
文献标志码:
A
摘要:
利用化学氧化法使苯胺在 Ag/AgCl 表面原位聚合,制备了聚苯胺银/氯化银复合材料(PANIAg/AgCl)。采用X射线衍射(XRD),紫外可见光谱(UVvis)对该复合材料进行表征。然后以甲基橙(MO)为模拟污染物,对比研究了 Ag/AgCl 和 PANIAg/AgCl 对该模拟染料废水的光催化降解活性。结果显示,光照 30 min 后,单独的 Ag/AgCl 对 MO的降解率约为65%;而 PANIAg/AgCl 对MO的降解率达到了99%。循环使用4次, PANIAg/AgCl对MO 的降解率不变。
Abstract:
Polyanilinesilver/silver chloride (PANIAg/AgCl) composite is produced from situ polymerization of aniline on the surface of silver chloride by the method of chemical oxidation.The samples are characterized by Xray diffraction (XRD) and UVvis diffuse reflectance spectroscopy.Then,a comparative study of the photocatalytic degradation activity of Ag/AgCl and PANIAg/AgCl toward methyl orange (MO) as the simulated pollutant is carried out. Experimental results show that the degradation rate of Ag/AgCl toward Mo is 65% when singularly used whereas that of PANIAg/AgCl reaches 99%.In addition,its degradation rate remains the same even after been cycle used for four times.

参考文献/References:


[1]朱明山,刘鹏磊,刘鸣华.银/卤化银:一类新型等离子体光催化剂[J].化学进展,2013,25(2/3):209-220.
[2]DONG R F,TIAN B Z,ZENG C Y,et al.Ecofriendly synthesis and photocatalytic activity of uniform cubic Ag@AgCl plasmonic photocatalyst[J].The Journal of Physical Chemistry C.2013,117:213-220.
[3]SONG L M,LI Y M,ZHANG S N,et al.Synthesis and characterization of Bi3+dopedAg/AgCl and enhanced photocatalytic properties[J].The Journal of Physical Chemistry C.2014,118:29777-29787.
[4]QIAO R,MAO M M,HU E L,et al.Facile formation of mesoporous biVO4/Ag/AgCl heterostructured microspheres with enhanced visiblelight photoactivity[J].Inorganic Chemistry.2015,54:9033-9039.
[5]LUO G,JIANG X,SHEN Q,et al.Facile fabrication and enhanced photocatalytic performance of Ag/AgCl/rGO heterostructure photocatalyst[J].ACS Applied Materials & Iterfaces,2013,5,2161-2168.
[6]CHEN Y H,FRANZREB M,LIN R H,et al.Platinumdoped TiO2/magnetic poly(methyl methacrylate) microspheres as a novel photocatalyst[J].Ind.Eng.Chem.Res,2009,48:7616-7623.
[7]NADA M D,SANJA T,LIU Y Z,et al.Nanostructured TiO2/polypyrrole for visible light photocatalysis[J].The Journal of Physical Chemistry C.2013,117:15540-15544.
[8]JU W J,SE R K,LI F,et al.SprayOn polyaniline/poly(acrylic acid) electrodes with enhanced electrochemical stability[J].ACS Applied Materials & Iterfaces,2015,7:24150-24158.
[9]MELAKU W,YADAV O,KEBEDE T.Photocatalytic removal of methyl orange dye by polyaniline modified ZnO using visible radiation[J].Science,Technology and Arts Research Journal,2014,3(2):93-102.
[10]MOUMITA C,HSIAO F W,NASKAR B,et al.Surfactantassisted synthesis and characterization of stable silver bromide nanoparticles in aqueous media[J].Langmuir,2012,28:7282-7290.
[11]LIU X,LI Z,ZHANG Q,et al.CuO nanowires prepared via a facile solution route and their photocatalytic property[J].Materials letter,2012,72:49-52.
[12]XU H,LI H,XIA J,et al.Onepot synthesis of visiblelightdriven plasmonic photocatalyst Ag/AgCl in ionic liquid[J].ACS applied materials & iterfaces,2011,3(1):22-29.
[13]Una B,Igor P,Miodrag M,et al.Interfacial synthesis of goldpolyaniline nanocomposite and its electrocatalytic application[J].ACS Applied Materials & Iterfaces,2015,7,28393-28403.
[14]Gao Y,Shan D,Cao F,et al.Silver/polyaniline composite nanotubes:onestep synthesis and slectrocatalytic activity for neurotransmitter dopamine[J].J.Phy.Chem.C.2009,113,15175-15181.
[15]ZHANG H,ZHU Y F.Significant visible photoactivity and antiphotocorrosion performance of CdS photocatalysts after monolayer polyaniline hybridization[J].J.Phy.Chem.C.2010,114,5822-5826.

备注/Memo

备注/Memo:

收稿日期:2016-07-20基金项目:四川省教育厅基经项目(10ZA022)
作者简介:夏林(1991—),男,四川广安人,硕士研究生,主要从事精细化学品合成及应用研究。
通信作者:詹豪强(1963—) ,男,福建平潭人,教授,主要从事高分子材料系物理有机化学研究。E-mail:1276554568@qq.com
引用本文:夏林,詹豪强,蒋晓慧.PANIAg/AgCl的制备及其光催化性能的研究[J].西华师范大学学报(自然科学版),2017,38(1):63-67.[XIA Lin,ZHAN Haoqiang,JIANG Xiaohui.On the synthesis of PANIAg/AgCl and its photocatalytic properties[J].Journal of China West Normal University(Natural Sciences),2017,38(1):63-67.]PANIAg/AgCl的制备及其光催化性能的研究
更新日期/Last Update: 2017-03-20